全文获取类型
收费全文 | 28589篇 |
免费 | 4873篇 |
国内免费 | 4105篇 |
专业分类
化学 | 21464篇 |
晶体学 | 480篇 |
力学 | 1660篇 |
综合类 | 334篇 |
数学 | 3025篇 |
物理学 | 10604篇 |
出版年
2024年 | 22篇 |
2023年 | 465篇 |
2022年 | 620篇 |
2021年 | 905篇 |
2020年 | 1153篇 |
2019年 | 1136篇 |
2018年 | 947篇 |
2017年 | 916篇 |
2016年 | 1401篇 |
2015年 | 1371篇 |
2014年 | 1632篇 |
2013年 | 2174篇 |
2012年 | 2706篇 |
2011年 | 2786篇 |
2010年 | 2013篇 |
2009年 | 1853篇 |
2008年 | 2094篇 |
2007年 | 1767篇 |
2006年 | 1636篇 |
2005年 | 1480篇 |
2004年 | 1169篇 |
2003年 | 987篇 |
2002年 | 1059篇 |
2001年 | 761篇 |
2000年 | 666篇 |
1999年 | 583篇 |
1998年 | 422篇 |
1997年 | 371篇 |
1996年 | 353篇 |
1995年 | 314篇 |
1994年 | 274篇 |
1993年 | 235篇 |
1992年 | 223篇 |
1991年 | 195篇 |
1990年 | 177篇 |
1989年 | 136篇 |
1988年 | 115篇 |
1987年 | 72篇 |
1986年 | 81篇 |
1985年 | 88篇 |
1984年 | 53篇 |
1983年 | 43篇 |
1982年 | 31篇 |
1981年 | 27篇 |
1980年 | 10篇 |
1979年 | 9篇 |
1974年 | 6篇 |
1966年 | 2篇 |
1957年 | 8篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 359 毫秒
21.
22.
Si-Yang Feng Tao Zheng Ai-Jing Sun Zuo-Xiang Wang 《Molecular Crystals and Liquid Crystals》2019,692(1):43-52
AbstractComplexes of [CdL2(NO3)2]·1.5H2O and [Ag2(μ-L)2(NO3)2] were synthesized by the reactions of 2-p-methylphenyl-5-(2-pyridyl)-1,3,4-thiadiazole (L) with Cd(NO3)2·4H2O and AgNO3, respectively. Their structures were determined by single crystal X-ray diffraction. The photophysical property and thermal stability were characterized by FT???IR, UV???Vis absorption, fluorescence, and thermogravimetric analysis (TGA). Both complexes belong to the triclinic system with space group p???1. The central metal of [CdL2(NO3)2]·1.5H2O has a distorted octahedral geometry [CdN4O2], while two central Ag(I) atoms of [Ag2(μ-L)2(NO3)2] exhibit distorted tetrahedral geometries [AgN3O]. 相似文献
23.
24.
在EAST装置上安装了X模极化W波段多道相关反射仪,用于测量等离子体芯部密度涨落。该诊断利用低损耗(<3dB)多工器将4个不同频率(79.2GHz,85.2GHz,91.8GHz和96GHz)的微波耦合在一起,通过同一个天线发射。反射波由两个极向分离(~5cm)的天线接收,通过下变频技术实现外差测量。通过对两个极向天线接收的信号进行相关分析,获得芯部湍流垂直速度。对2018年低约束模式(L模)放电进行分析发现,在电子回旋共振加热(ECRH)等离子体中,芯部湍流垂直速度在电子逆磁漂移方向。而在注入同向中性束(co-NBI)后,芯部湍流垂直速度变为离子逆磁漂移方向。 相似文献
25.
Chao Liu Liying Wang Lin Yang Famei Wang Chunhong Xu Jingwei Lv Guanglai Fu Xianli Li Qiang Liu Haiwei Mu Tao Sun Paul K. Chu 《Physics letters. A》2019,383(25):3200-3206
A single-polarization filter comprising a gold-coated photonic crystal fiber based on surface plasmon resonance is designed and investigated. The pattern matching and coupled polarization characteristics analyzed by the full-vector finite element method (FEM) and losses at 1,540 nm are achieved to 1,016.01739 dB/cm (x-pol core mode) and 33.81917 dB/cm (y-pol core mode). The crosstalk (CT) value of the 1,540 nm band is ?853.12653 dB for fiber length and the bandwidth is 850 nm. The working wavelength of the filter ranges from 1,280 nm to 1,540 nm by varying the diameter of outer air holes (), the diameter of inner air holes (), the metal film thickness (t), as well as the liquid refractive index (n). 相似文献
26.
Alessandro Morando Paola Trebeschi Tao Wang 《Journal of Differential Equations》2019,266(9):5397-5430
We show the short-time existence and nonlinear stability of vortex sheets for the nonisentropic compressible Euler equations in two spatial dimensions, based on the weakly linear stability result of Morando and Trebeschi (2008) [20]. The missing normal derivatives are compensated through the equations of the linearized vorticity and entropy when deriving higher-order energy estimates. The proof of the resolution for this nonlinear problem follows from certain a priori tame estimates on the effective linear problem in the usual Sobolev spaces and a suitable Nash–Moser iteration scheme. 相似文献
27.
Metabolic profiles of dioscin in rats revealed by ultra‐performance liquid chromatography quadrupole time‐of‐flight mass spectrometry 下载免费PDF全文
He Zhu Jin‐Di Xu Qian Mao Hong Shen Ming Kong Jian‐Ping Chen Song‐Lin Li 《Biomedical chromatography : BMC》2015,29(9):1415-1421
Dioscin (DIS), one of the most abundant bioactive steroidal saponins in Dioscorea sp., is used as a complementary medicine to treat coronary disease and angina pectoris in China. Although the pharmacological activities and pharmacokinetics of DIS have been well demonstrated, information regarding the final metabolic fates is very limited. This study investigated the in vivo metabolic profiles of DIS after oral administration by ultra‐performance liquid chromatography quadrupole time‐of‐flight mass spectrometry method. The structures of the metabolites were identified and tentatively characterized by means of comparing the molecular mass, retention time and fragmentation pattern of the analytes with those of the parent compound. A total of eight metabolites, including seven phase I and one phase II metabolites, were detected and tentatively identified for the first time. Oxidation, deglycosylation and glucuronidation were found to be the major metabolic processes of the compound in rats. In addition, a possible metabolic pathway on the biotransformation of DIS in vivo was proposed. This study provides valuable and new information on the metabolism of DIS, which will be helpful for further understanding its mechanism of action. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
28.
29.
Cuixia Cui Yong Gao Dr. Jun Li Chao Yang Meng Liu Prof. Dr. Huile Jin Prof. Dr. Zhenhai Xia Prof. Dr. Liming Dai Prof. Dr. Yong Lei Prof. Dr. Jichang Wang Prof. Dr. Shun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(20):8002-8007
Although tremendous efforts have been devoted to understanding the origin of boosted charge storage on heteroatom-doped carbons, none of the present studies has shown a whole landscape. Herein, by both experimental evidence and theoretical simulation, it is demonstrated that heteroatom doping not only results in a broadened operating voltage, but also successfully promotes the specific capacitance in aqueous supercapacitors. In particular, the electrolyte cations adsorbed on heteroatom-doped carbon can effectively inhibit hydrogen evolution reaction, a key step of water decomposition during the charging process, which broadens the voltage window of aqueous electrolytes even beyond the thermodynamic limit of water (1.23 V). Furthermore, the reduced adsorption energy of heteroatom-doped carbon consequently leads to more stored cations on the heteroatom-doped carbon surface, thus yielding a boosted charge storage performance. 相似文献
30.